The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Alkenes,polyenes+radicals / Alkene radicals / CH2=CH / FahrLaufer(1990)_298K_164.71,168.33nm(max)

DATAFILE: CH2=CH_FahrLaufer(1990)_298K_164.71,168.33nm(max).txt
NAME: vinyl radical
FORMULA: CH2=CH
AUTHOR(YEAR): FahrLaufer(1990)
T: 298K
λ: 164.71,168.33nm(max)
BIBLIOGRAPHY: A. Fahr and A.H. Laufer, "Direct measurements of the combination and disproportion of vinyl radicals", J. Phys. Chem. 94, 726-729 (1990); DOI: 10.1021/j100365a040
COMMENTS: Absorption measurements following vacuum-UV flash photolysis of divinylmercury

Absorption cross sections at the maxima of two VUV absorption bands

The earlier results, (6.70 ± 2.03)e-17 and (4.55 ± 2.03)e-17, of

A. Fahr and A.H. Laufer, "Ultraviolet absorption of the vinyl radical and reaction with oxygen", J. Phys. Chem. 92, 7229-7232 (1988),

have been corrected

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